Point-contact semiconductor photocell



March l5, 1960 J. H. MYER POINT-CONTACT sEMrcoNDUcToR PHo'rocELL 5 Sheets-Sheet 1 Filed April 5, 1955 A76, la,

INVENTOR.

March 15, 1960 J. H. MYER POINT-CONTACT sEmcoNnucToR Px-xo'rocm.

5 Sheets-Sheet 2 Filed April 5, 1955 n y` i W M N hw m, w .a V 0 m n Mm MQ 7 H N N N 5 N N U M M N m u a W Y W N N N w s M 5 kwwwu M l. f a w m a v f f 5 C QS ux WWNNN QQ; /vf W 4 y f//N f/h p nl! a J. H. MYER POINT-CONTACT sEMcoNDUcToR PHoTocELL March l5, 1960 5 Sheets-Sheet 3 Filed April 5, 1955 -/O/V Af. A44/2 INVENTOR.

March 15, 1960 J. H. MYER POINT-CONTACT SEMICONDUCTOR PHOTOCELL 5 Sheets-Sheet 4 Filed April 5, 1955 ./O/V H. MVEZ INVENTOR.

March 15, 1960 J. H. MYER POINT-CONTACT sEmcoNDuoToR PHoTocELL 5 Sheets-Sheet 5 PolNr-coNrAcr sEMlcoNnUcroR PHorocELL .lon H. Myer, Los Angeles, Calif., assgnor to Hughes Aircraft Company, Culver City, Calif., a lcorporation of Delaware Application April 5, 1955, Serial No. 499,292

7 Claims. (Cl. Z50-211) This present invention relates to photocells and more particularly to point-contact semiconductor photocells.

Photocells are usually divided into two distinct classes, ene type being a photoelectric cell and the other a photoconductive cell. The device of the present invention may alternately be used as either a photoelectric or photoconductive cell, depending upon the external conditions established. A photoelectric cell will generate a current in a closed electrical circuit which is proportional to the intensity of the radiant energy received by the cell. On the other hand, a photoconductive photocell will change its electrical resistance with illumination and as it has nonlinear characteristics it will rectify an applied A.C. signal. The photoelectric or photoconductive phenomenon occurring in a semiconductor point-contact photocell may be explained in relatively simple terms, while a rigorous treatment of the subject requires quantum mechanics, calculations and equations. It might further be added that much is yet left to be discovered and explained in the field of semi-conductors in general and semiconductor photocells invparticular. The simple explanation to follow requires a familiarity with the terms relating to semiconductors defined in the October, 1954 issue of Proceedings of the IRE, pages 1506 through 1508.

Semiconductors, such as germanium, silicon, germanium-slicon alloy, indium-antimonite, aluminum-antimonite, gallium-antimonite, indium-arsenite, aluminumarsenite, gallium-arsenite, lead-sulfide, lead-telluride, leadselenide, cadmium-sulfide, cadmium-telluride, cadmiumselenide, or others hereinafter to be discussed, have been found to be extremely useful in electrical devices for translating electromagnetic energy, such as light or radiant energy for the generation or control of electric currents. In particular, these semiconductor devices have been utilized for sensing light and other forms of radiant energy and for amplifying or rectifying electrical input signals.

Basic to the theory of operation of semiconductor devices is the concept that current may be carried in two distinctly different manners; namely, conduction by electrons or excess electron conduction, and conduction by holes, or deficit electron conduction. The fact that electrical conductivity by both of these processes may occur simultaneously and separably in a semiconductor specimen aifords a basis for explaining the electrical behavior of semiconductor devices. lOne manner in which the conductivity of a semiconductor specimen may be established is by the addition of active impurities to the base semiconductor material.

In the semiconductor art, the term active impurities is used to denote those impurities which aiect the elecrical characteristics of a semiconductor material as distinguished from other impurities which have no appreciable effect upon these characteristics. Generally, active impurities are added intentionally to the semiconductor material for producing single crystals having predetermined electrical characteristics.

States Patnt Active impurities are classified as either donors, such as antimony, arsenic, bismuth, and phosphorous, or acceptors, such as indium, gallium, thallium, boron, and aluminum. A region of semiconductor material containing an excess of donor impurities and yielding an excess of free electrons is considered to be an impuritydoped N-type region. An impurity-doped, P-type region is one containing an excess of acceptor impurities resulting in a deficit of electrons, or stated differently, an excess of holes. ln other words, an N-type region is one characterized by electron conductivity, whereas a P-type region is one characterized by hole conductivity. Presently it is thought that when a photon of radiant energy (either in the heat or infra-red, or in the light or visible portion of the electro-magnetic wave spectrum), strikes the surface of a semiconductor material, anelectron and corresponding hole are produced as a pair. It is the ilow of either these holes or electrons which produces conduction in the device which utilizes an N-type crystal as herein arbitrarily described. This conduction is mostly caused by holes which because of being surrounded by N-type impurity atoms are also called minority carriers. The generation rate, i.e., the time rate of creation of electron-hole pairs is a function of the number of photons which impinge upon the semiconductor crystal and which are not reflected at the surface of the crystal. Unfortunately, after the electron-hole pairs are thus produced, there is a tendency for them to recombine. That is, the minority carrier has a tendency to recombine with an impurity atom to cause both the electron and hole to disappear. This recombination has been theorized to depend at least in part upon Athe following parameters: perfection of the semiconductor crystal, resistivity of the semiconductor crystal, surface condition of the semiconductor crystal, or surface-to-volume ratio of the semiconductor crystal. In order to reduce the recombination rate Ait has been found desirable to place the collector junction, which is the point contact, close to that portion of the crystal at which the light or radiant energy impinges. When the point contact is too close to the location on the semiconductor crystal where the light impinges, both a production and a theoretical problem are encountered. If the crystal is made too small then in the manufacture of the photocell the pointed end ofthe Whisker element may entirely miss striking the crystals so that there will in fact be no point contact made at all. Further, even though a small crystal permits a more eicient collection of carriers a larger crystal permits'a more eiiicient collection of light. As an upper limit, the crystal cannot be made too large, else there will be too great a distance between the point contact position and the point or portion of the crystal wherein the .photons impinge. Minority carriers will therefore have too great a distance to travel to the aforementioned collectorpoint contact. As a result, since minority carriers tend to diffuse and recombine with impurity atoms in the crystal, very few will actually reach the point contact to produce any appreciable conduction. The presently accepted theory suggests that the greatest loss of minority carriers by recombination takes place at the surface of the crystal. Accordingly, the most advantageously `designed crystal configuration, to reduce the degree of recombination, would call vfor the use of a spherically-shaped crystal. This is true because the ratio of surface-to-volume of a sphere "is the smallest of any possible geometrical configuration.

It would thus appear that a photocell making use of a spherical semiconductor crystal with an associated pointcontact would be the best solution to the aforementioned problem, namely, it would have the lowest possible reclcaacuo.

combination rate.. is true,,buttoamanypractical production problems are pvnesented which preclude the use of spheres or near-spherical shapes as the semiconductor. crystalabcdv. rsSome ofthe `clitneulties en countered areigvolvedrin the; vtannins.oftspheres Ito` begin with and the subsequent lirlabilityyto ,bringth'e-pointcontact in pressureengagement ...with ithespnere without slipping and scratching theslurface thereof.. .,:Any imperfection of .a crystallinesolid, Xthat is ,any-.deviation in Ithe structure, evenLthat'causedgbyaiscratch on the surface by a Apoint .contact-,.will greatly/reduce theeiiicient operationof a devicausing suchtatpoint.contacts .t

Many of thelpresent art photocellswhich 'actleitherlas rectiliers or photoelectric devices. cannotfbemade 'small enough.. tot be. advantageously sut-ilized. in .'Jrriiniaturized packages .0L-systems. A further "disaidvantage of. .many of thelpre'sent .art/*aphotocells isatheir Iperviousness'to moisture. .Stillianother inherentgdisadvantage to.- be-encountered. by. .all of Atheepresent art devices is gthatithey are onlysensitive to 'a directed or `un'idirectional v`smirce of:liglit.energy..

AFurther, manyioi tlie present .devices-have vtheir use limitedto either photoconductive orphotoele'ctric operation. Most ofthe vpresent'art devices are also sensitive toshoclcand moisture.

, Accordingly, itis therefore `the 'prix-nary vobject of this invention to provide fan improved and 'exceedingly small point-contact photocell.

n Y -l i `Another object of` this invention is to provide a'glassfusion photocell which is hermetically sealed and therefore impervioustomoisture. Y l' A furtherobject `of this invention is ito "provide a photocell of extremely rugged construction, which will not be detrimentallyaifected by being subjected'to Aa1st`ar`idard droptest, such asa fall from a height of 30 inches onto amaplevi'loor. A

`Still another object of this invention is to providean improved photoconductive celladaptecl to operate with a bias-.voltageconnected across the electrodesto provide an output current whichis representative iftheF radiant energy impinging uponothe cell, with `'a minimum of v residual 'change-in thedark current.

Still another object of this invention is Atofprovide va photocell which'li'as 360 degrees angularsensitivity about its axis. l A M' Y j A` still ifurthen'object orf, this invention` is to provide a photocell which rhas `'a sensiitvity which is inherently ad justable. f A l" i e o Y, V l Y lAstill further object of this invention istoprovide an improvedphotocell which is v'adaiite'cl to operate with a sourceof alternating "current connected across' theelecn trodes toprovide a rectiiie'doutput voltage in 'response to radiant energyrimpinlgirg iipn thefc'ell. Y A

In the vpresent invention Va small region adjacent the point contact of a semiconductor specimen 'of oneconductivity type isconvertedntoaa semiconductorgmaterial of the other conductivity type' by dopingvthisre'fgion with atomsfof an active impurity from the metallic tive Whisker element making fa vpointcontact engage ment with `the specimen. More particularli/,fi tsilient Whisker elementincludiii'g 'an/"active impurity of onetypc is pressed in contact against an intrinsic or doped semi conductor crystal including Yan; active impurity'of the other type, and an electrical-forming Vcurrent ispassed through the Whisker and crystal to produce a doped region, in cludi'rig an excess ofatoms of zSlaiduone type off/active impurity in theportion of the crystal adjacentrthke point contact, l'and theebychan g the adjacent region to the opposite'co'iidiie'tivity A Y 'Accordiiigio one''e a Whisker elementr containing indium is vutil establishing Afa doped ,P- t'ype regionin a dopedYN-type germanium sr'ystslpeimen 1.1.1. this embsdimentthe indium mayb ated jon` sker ofa Suitable'rnetafprior to seiu'ja` semiconductor device,

or the indium. ,may be fused into the adiacent surface region of the N-type germanium crystal.

Another method for creating a region of opposite conductivity in the area adjacent the point contact is to pro` vide a Whisker which includes a resilient metallic material alloyed with an acceptor impurity, such as aluminum, gallium, or indium, for establishing such doped P-type region in th'eN- type semiconductor specimen.

I The present,invention makes use of a substantiallyI cube-shaped vcrystal which for a given volume has a relatively low surface area, simultaneously allowing direct contact between the crystal and the point Contact without resulting in slippage between the`point contact and the crystal during assernhiy.v causing an imperfection in the face of the crystal. The 'term substantially cube-shaped as used hereinafter also includes a cylindrical crystal having parallel upper an lower surfaces which has been exposed to an etching :process which by virtue of itsfpreferential- -naturetrevealsothc cubical lattice of the semiconductorcrystal material. This sometimes results in a crystal whosesides tendto assume a bulging cubo corr guration aftertheetching process even though it was initially -a cylindenorfa sphere. It has been found by laboratory experimentation that a preferred size for such acrystal bearing in mind the previously explained upper and lower limits asto Ysize and shape, and further assuming optimum values of low surface recombination velocity and low bulk recombination is approximately 'a cube whoseedgesfmeasure between 0.1 and 2.0 millimeters.

In manyofthe prior art photocells 4theproblem of recombination @was recognized, but the solution therein taughtV was to focus, the light at a point-directedat the point.. contact thus Yconsiderably reducing the distance that theminoritycarriers Aneed travel to the point con tact. This practice has been found for many purposes to be undesirable because adjacent the point where the Whisker makes contact with the crystal a minute junction is created during lthe. forming operation. In case the device isbiased to provide photoconductive operationv a large; potential gradient is established at this junction. The region where this large potential gradient appearshat the surface is very susceptible to contamination by trace impurities,and these'impurities in turn are semi-'permanently aifected by light.` This semi-permanent effect may noticeably alter the dark current of the photocell for prolonged periods ranging to hours. Of course this reduces the reliability of such devices. To sum up, the reduction in reliability `of a vdevice such asv a biased photoconducting celll is due to a residual change in dark currentafter-illumination. f I l v In thecase ofthe semiconductor cube this effect is eliminated sincethe light impinges on the sides ofthe cube while the miniature junction with itslarge potential gradient is in the .shadef This is due to the fact that the region where the Whisker impinges is only exposed to a small amountof glancing radiation due to the angle the i'r'npin'ging light makes therewith.

In accordance with a preferred embodiment of the present invention there is provided a semiconductor crystal, va'resilient whisker element engagingl one surface of the crystals, anda hollow, hermetially-sealed, vitreous envelopeiricasing the pointcontact and crystal, the crystal preferably having a cubical shape. T he vitreous envelope is made transparentto radiant energy so that any such energy will not thereby be impeded from impinging upon the surface orsurfaces yof the incased germanium crystal at which itis directed. o n

The .ncvelfteswresvhirh are believed t@ be. sharestiisfictif the. Il remirrbcth ,s-t0 ,its Organization aad-.oramai offp altio, ,t 6`get her` withfurtherobjects andadvantages thereof, willbe better understood fromI the following description I considered.firi- -l connection with accompanying drawings in which severalembodiments of the invention are ustfafed 5y Way 0f @temples-.pit is tabs expresso understood, however, that the drawings are for the purposes of-illustration and exampleonly, and are not intended asa denition of the limits of the invention.

In the accompanying drawings:V

Fig. la is a graph showing the energy levels in a germanium crystal;

Fig. lb is a graph indicating the energy levels and charge carriers present when impurities are added to a germanium crystal:

Fig. 1c is a graph showing the conditions which obtain when a relatively abrupt internal junction exists between N- and P-type materials.

Fig.'2 is an enlarged isometric view showing the preferred embodiment of the photocell of the present invention encapsulated in a vitreous envelope and hermetically sealed therein. Y

Fig. 3 is an isometric view showing in detail the elements incased in the vitreous envelope shown n Fig. 2.

Figfla is a circuit diagram of one embodiment of the photocell wherein it is biased by an alternating current.

Fig. 4b is a graph showing, as a function of time, the voltage developed across the electrodes of the photocell ofvFigr4a when such photocell is not illuminated.

Fig.` 4c is a graph showing, as a function of time, the voltage `developed across the photocell of Fig. 4a when the photocell is illuminated.

Fig. 5a is a circuit diagram of another embodiment of the photocell utilized as a photoelectric generator without a biasing voltage.

Fig. 5b is a graph showing, as a function of luminosity, the current developed by the photocell connected as shown in Fig. 5a.

Fig. 6a is a circuit diagram showing a D.C. biased photocell.

Fig. 6b is a graph showing current as a function of applied bias voltage for the circuit illustrated in Fig. 6a under three different conditions of illumination.

Fig. 7 is an isometric view of the photocell of Fig. 2 showing how it may be used to indicate the presence of a hole in a punched hole card.

Fig. 8a is an isometric view of the photocell of Fig. 2 utilized with a half-cylinder reector.

' Fig. 8b is an visometricview of the photocell of Fig. 2 utilized with a paraboloid reector.

Fig. 8c`is an isometric view of the photocell of Fig. 2 having a spherical lens attached thereto.

Fig. Sdis an isometric view of the photocell of Fig. 2 having a cylindrical lens attached thereto.

Fig. 9 is a cross-section view of another embodiment of the photocell of the present invention wherein the crystal is tilted within the vitreous envelope, and

Fig: 10 is anv isometric View of a modification of the present invention wherein the crystal is supported at opposite points within the vitreous envelope.

For the purpose of clarity, the invention will be discussed in connection with point-contact, semiconductor photocells in which the monatomic semiconductor crystal is N-type germanium andthe point contact is doped with a P.type active impurity. `It is to be expressly understood, however,that the invention is equally applicable to the utilization of aP-type germanium crystal having a point contact doped with an N-type active impurity, or with any other type semiconductor, showing suitable light sensitivity, such as N- or P-type silicon, N- or P-type silicongermanium,` alloy and other crystals hereinbefore mentioned, as well as larger area junctions instead ofthe Whisker point contact.

j, Referring now to the drawings, wherein like reference characters designate like parts throughout the various gurestthere are shown in Figs. la, 1b, and 1c graphs illustrating the physical phenomena which explain the operation of semiconductor 'photocells It'm'ay be taken as axiomatic that a periodical array of xed atomic charges produces a series of bands of energy levels in which the associated electrons may move. Fig. 1a..'i1lustrates this phenomenon diagrammatically for a will be generated in the N-type crystal.

single crystal of germanium.k Three bands are shown; the upper band being the conduction band, the middle band called the energy gap or forbidden band, and the lower band being called the valence band.

After the germanium has been completely refined, controlled amounts of donor or acceptor impurities may bel introduced into the germanium. A single N-type germanium crystal is then grown. The energy level diagrarnk will thenappear for this single crystal of germanium, as shown .in Fig. 1b. Therein the donors and acceptors are assumed to be completely ionized.

As indicated in Fig. 1b, the energy levels of the donor atoms indicated by a cross in a circle lie near the conduction band and the energy levels of the acceptor atoms represented by a minus sign in a circle lie near the almostfilled valence band. Whenever the number of donor ions exceeds the number of acceptor ions electrical conduction in the crystal will be mainly by the excess electrons represented as minus signs without a circle in the conduction band in Fig. 1b. 1f the number of acceptor-ions exceeds the number Aof donor ions conduction will mainly be due to the positive holes represented as plus signs without a circle in Fig. lb created in the otherwise filled valence band of electrons. The charged impurity ions, (donors and acceptors) are fixed in position in the crystal and are not free to move.

A single crystal of germanium which contains a relatively*V abrupt junction between N- and P-type material exhibits rectifying properties. This is shown diagrammatically in Fig. 1C. ln this diagram electrons like to ow downhill to regions of lower potential energy (more positive)v and holes like to flow uphill like air bubbles in a liquid. The area wherein there exists an N-P junction exhibits the property that any potential applied across the crystal will appear mainly across this junction region. If the N region, shown on the left, is made positive, the electrons would like to ow from right to left, "down the junction hill. But, there are few electrons on the right to tlow downhill and few holes on the left to ow uphill, thus little current llow can result. This is termed the direction of diicult current ow or the reverse direction. lt is the direction in which a photocell is biased. If light falls in the vicinity of the junction, i.e.on the N-type side of the junction, electron-hole pairs While the excess electrons thus-generated will be added to the existing excess electrons, the holes rwill be swept toward the right, resulting in a photo current.

Reference is now made to Fig. 2 wherein there is shown` one embodiment of a photocell according to this invention. The photocell is shown as a completed package, being incased within a vitreous or glass envelope 20. A complete description of this envelope and itsv method of manufacture may be found in U.S. Patent 2,694,l68,'entitled Glass-Sealed Semiconductor Crystal Device, by H. Q. rNorth et al., issued November 9, 1954. As illustrated in Fig. 2, radiant energy directed at the photocell is received by a crystal 11 from a light source indicated by arrows 21. ln case the photocell is operated with a bias the light received on top crystal surface 16 is effective, or alternatively light may be received on crystal surfaces 12, 13, 14, and 15. In the case of photoelectric or photovoltaic operation it is permissible to illuminate only the upper surface 16 in the vicinity of a Whisker element y17 for maximum sensitivity, Whisker element 1'7' being substantially S-shaped and of a resilient metal. Crystal 11 preferably has the shape of a cube as shown.

In Fig. 3 there is shown an isometric view of the photo-' cell illustrated in Fig. 1 without incasing glass envelope 20. As previously mentioned the invention will hereafter be disclosed in connection with a point-contact semiconductor device in which N-type germanium is the material of crystal 11, it vbeing expressly understood, however,v that the inventionis equally applicable to the utilization of P-type germanium or any other semiconductor material the crystal.

higher than that at point 47, while the impressed potential across cell 26 has been increased 50-fold.

Curve 31 indicates the current-voltage relationship for intermediate illumination. Curve 32 is a higher light intensity curve for current versus voltage with voltage at point 48 showing the photogenerator or photovoltaic eiect described previously.

In Fig. 7 there is shown one application of the photocell 26 disclosed in the present invention whereby it is used to discern the occurrence of a hole 35 in a standard punched-hole card 36 employed in modern electronic computers. While it is true that infrared light will pass through card 36, even where no hole exists, the light will be scattered by the paper. On the other hand, when the light beam from source 40 focused by lens 37 appears at a portion of card 36 wherein a hole 35 is punched out the light beam passes through unimpeded, i.e., it is not scattered. As a result of this phenomenon, it is at once apparent that photocell 26 when so used can easily distinguish the existence of a hole from an opaque portion of card 36. This is possible because the output of photocell 26will vary with the light intensity impinging upon its crystal 11 as previously explained. This variation is caused by the diierence between the focused light intensity and the scattered light intensity.

Photocell 26 may be used also in another specialized application with either a P- or N-type germanium golddoped crystal for use in the far infrared region. Alternatively cobalt or iron may be used as the doping agent for the crystal instead of gold. The use of an N- or P- type germanium photocell without the addition of any of the above doping agents results in a device having a spectral response which is effectively sensitive only to radiant energy up to a wave length of approximately 2 microns while the goldor iron-doped device is sensitive to greater Wave lengths.

The addition of these doping agents extends the sensitive region far into the infrared region according to the physical phenomena described in an article by Roger Newman, entitled Photoconductivity in Gold-Germanium Alloys, in Physical Review dated April 15, 1954, pp. 278-285. v

Fig. 8a illustrates how a half-cylindrical reflecting surface 44 may be advantageously employed with the present invention to direct received radiant energy from a source indicated by arrow 50 in a controlled manner, at photocell 26, thus utilizing all four sensitive surfaces 12, 13, 14, and of crystal 11.

Alternatively a paraboloid-shaped reector 45 presented in Fig. 8b illustrates another manner for directing light from a source indicated by arrow 50 to the four surfaces 12, 13, 14, and 15 of the photocell 26. Herein again all four sensitive surfaces of the crystal are utilized.

Referring now to Fig. 8c therein is shown another embodiment of the present invention. Basically, therein photocell 26, ncased in glass envelope has aixed to it a spherically-shaped lens or bead 38 of suitable index of refraction at a point on the envelope 20 which is opposite the region of maximum sensitivity of the crystal 11 herein arbitrarily designated surface 15. The word aixed is intended to include either temporary or permanent attachment of bead 38 to envelope 10. Temporary attachment may include the use of a simple, mechanical clip.

By a suitable index of refraction it is meant that value which will cause any light directed at the lens to continue therethrough finally impinging upon crystal 11, instead of A possibly being reflected back out of the lens away from ead 38 may be made integral with glass envelope 16 by being permanently aixed thereto by means of cement 39 whose index of refraction is substantially equal to that of the spherical lens. found that the addition of this lens increases the directivity of the device, resulting in an increase o f vsensitivity It has been up to 6G() percent for light directed toward thespherical lens.

YAn alternative manner of increasing the sensitivity of photocell 26 is illustrated in Fig. 8d. A cylindrical lens 42 having a suitable refractive index is axed as described above upon envelope 26 in a plane parallel vto the axis'of the device. Alternatively, cement 39 may be employed to mount the cylindrical lens 42 which should have a suitable index of refraction upon envelope 20. Here again the index of refraction of the cement if used is substantially equal'to that of the cylindrical lens, it being often desirable to only temporarily attach lens 42. A cylindrical light source 51 is shown for this arrangement.

In Fig. 9 there is shown another embodiment of the present invention wherein the crystal element v11 is shown to be tilted with respect to base. electrode 18, base electrode 13 still making contact with bottom surface 19 of crystal 11. In this embodiment of the invention light is directed at the area of the crystal where Whisker element 17 makes contact therewith only as shown by ar row 50.

This device will show the greatest directional sensitivity as a photoezectric generator since the minority carriers have to cover lan exceedingly short distance and will not recombine, while the residual detrimental effect due to the past history of photon excitation of crystal 11 Willfnot appear in the photogenerator application.

Whilespeciiic structure has been shown it should be apparent that many substitutions may be made without departing from the spirit of the invent-ion, for example, the crystal element 11 may be supported upon electrode 1S upon one of its points 49, as shown in Fig. 10. The opposite point wou`.d then be electrically joined to electrode 24 through leaf-spring contact 52. This modification of the invention would present a greater surface area of the crystal 11 to impinging light, and permit alternate methods of creating the collecting P-N function as discussed hereinabove.

There has thus been disclosed a novel semiconductor photocell which may be alternatively utilized as either a photogenerative or photorectier device which is extreme ly compact and rugged. l

What is claimed as new is:

l. A semiconductor photocell comprising: a semiconductive crystal having a substantially cubical shape, with a doped P-type region located substantially at the center of a first surface of said crystal; a Whisker element doped with an electrical-conductvity-type-determining impurity of an opposite type from that contained in the balance of said crystal and having one end thereof in the form of a point-contact welded to said first surface of said crystal at said doped P-type region; a iirst electrical conductor connected to the other end of said Whisker element; a second electrical conductor bonded to a second surface of said crystal, said second surface being located opposite said first surface; a hollow envelope wholly incasing said crystal and said Whisker element, and having fused hermetic seals with said r'st and second conductors for maintaining said conductors in their relative positions, said envelope having a vitreous transparent portion positioned with respect to said crystal for admitting radiant energy to the remaining four surfaces of said crystal which do not have electrical connections thereto, .whereby said photocell when utilized as a photorectifier exhibits approximately omnidirectional sensitivity to radiant energy impinging upon said four remaining surfaces.

2. A photocell comprising a crystal of semconductive material having a `substantially cubical form, having located substantially at the center of a first surface of said crystal a doped region of an opposite type from'that contained in the balance of said crystal; a Whisker element making a point electrical contact to said rst surface at said rst region; a first electrical conductor connected to said Whisker element; a secondelectrical conductor cr"y tal which do nothaveelectrical connections thereto,

whereby z sa'idfphotorcell 'when utilized as a photoelectric deyiee exhibits iiniforirl omnidirectional sensitivity to radiation inipingingponis'aid four remaining surfaces.

3. A `photoc'ell comprising: la semiconductor crystal having a :substantially cubical form; a Whisker element ivith :an active electrical-conductivity-typeideter- Aiiriptirityfof` the y'oppositetype from that contained i crystal andhaving loneend in the form of a point- 'or act"in"offcenter contactwith'a first surface of said eiys'taliand A'weldedthereto; a doped region in said crystal dispseatft'hepointwhere said whisker element makes Contact with said crystal, said doped region being of the 'onductivitytype of said active impurity; a first electrical cnduotor'comie'cted to the other end of said Whisker elen'ientgliauseeond 'electrical conductor engaging a second 'su'fa'cefof said'erystal located opposite vsaid first surface,

'ch'edgeiofsaid'crystal having a length in the range 011 to 2.05-inilliiteis',a'ridfa hollow moisture impervious enyoil nea'singsaid crystal'and said whiskerele- `nientand-lhav-ing fused hermetic-sealswith said first 'and 'sndeltrial Vconductors for maintaining said condc'teis in their? relative '1 positions, 'saidv envelope having 'aftransparentpertion positioned with respect to said crysvtal-foradinittingradiant energy to the remaining 'four -sr`facesfbfisaid crystal which'do not haveelectrical'con- 'ections thereto, whereby said photocell when utilized as Aailplotoelectric vdevice 'exhibits asymmetrical sensitivity -to radiation impingingupon-said four remaining surfaces.

4. The photocell defined in claim 3 wherein said semi- 'conductor crystal is silicon.

'5. l'hefphotocell defined in claim 3 whereinl said semiconductor :crystal is a `germanium-silicon lalloy.

6. A semiconductor photocell rcomprising: la-'Scrystal @senese body o'f Yserriiconfdu ct'ive .material ,lraving ,a substantially cubical `s'hape`a doped region ofan opposite type from that contained lin Jthe balance of ,said crystal body provided in 'said crystal 'and adjacent va'rst surface thereof; awhisker element doped with an yimpurity selected from the group consisting of donors and acceptors of the conductivity type-of said doped region ,and having one end thereof in'the form ofa point-contact welded to said first surface at said doped region; a first electrical conductor connected to the other end o`f said Whisker element; Aa secontielectrical conductor bonded to a .second surface ofisaid'cry'stal opposite said first surfaceya hollow moisture impervious envelope wholly incasing said crystal and said Whisker element and having fused hermetic seals lwith 'said first'a'ndssecond conductors in vtheir relative positions, saidrenvelope having a transparent portion positionedlwith respectLtossaid cubical crystal body for admitting radiant energy to'the remaining four surfaces of said cubical crystal body which do .not have electrical connectionsthereto; anda substantially spherical radiant energy `transmitting bea'd affixed to said envelope at apointlcoineident with Yone of said remainingfoursurfa'cesof said cubical crystal whereby said photocell when utilized 'as a photoelectric device establishes a potential gradient between 'said firstand second electrical conductors'proportional tocthe intensity ofradiant energy focused upon'that surfaceof said crystal located in register with' said. spherical bead. I

"7. The photocell defined in claim 6 Whereinpsaid radiant energy transmitting bead.,is cylindrically shaped.

'References Cited inthe file ofrthis patent \UNITED..STA1ES PATENTS 2,504,628 vBenzer Apr. 118," 1950 2,586,609 Burke Feb. 9, 1,952 l2,640,901 .Kinman June 2, 1953 -`2,677,106 'Haynes etal Apr. 27, 19154 691,736 IHaynes Oct. l2, 1954 2,694,168 North-et. al. Nov. 9, 1954 2,733,390 Scanlon v Jan. 21, 1956 2,735,919 Shower Feb. 2l, 1956 '2,818,536 .'Carmanetral ..-Dec 31,1957 

